Anomalous boron isotope effects on electronic structure and lattice dynamics of CuB₂O₄

Rea Divina Mero^1*, Chun-Hao Lai², Chao-Hung Du², Hsiang-Lin Liu¹

¹Department of Physics, National Taiwan Normal University, Taipei, 11677, Taiwan
²Department of Physics, Tamkang University, Tamsui, New Taipei City, 25137, Taiwan

* Presenter:Rea Divina Mero, email:readivina@gmail.com

Copper metaborate had a unique crystal structure and exhibited noteworthy magnetic phase transitions at 21 and 10 K. The electronic structure and lattice dynamics of copper metaborate Cu¹¹B₂O₄ single crystals were investigated and compared with the optical properties of CuB2O4, to assess the boron isotope effect. The optical absorption spectrum at room temperature revealed two charge-transfer bands at approximately 4.30 and 5.21 eV with an extrapolated direct optical band gap of 3.16 ± 0.07 eV. Comparing with the data on CuB₂O₄, the electronic transitions were shifted to lower energies upon the replacement of a heavier boron isotope. The band gap was also determined to be lower in Cu¹¹B₂O₄. Anomalies in the temperature dependence of the optical band gap were observed below 21 K. Furthermore, 38 Raman-active phonon modes were identified in the room-temperature Raman scattering spectrum of Cu¹¹B₂O₄, which were also observed in CuB₂O₄ with a shift to lower frequencies. No broadening caused by isotopic changes was observed. As the temperature decreased, phonon frequencies shifted to higher wavenumbers and the linewidth decreased. Anomalous softening in the Raman peaks below 21 K was also revealed.

Keywords: Strongly Correlated Electrons, Isotope Effects, Optical Properties